Luigi is generally easygoing and is very kind and considerate to those around him. Nevertheless, Luigi musters his courage for a couple of adventures in the Paper Mario series, showing bravery and determination when it is needed. He is often slightly cowardly and is terrified of ghosts according to his diary. Luigi is best described as the "underdog" of the Mario Bros., often going unnoticed due to his reluctant nature. " He's teased by Goombas and Koopas alike and is sometimes called "green mustache guy"." - Paper Luigi's trophy description in Super Smash Bros. But Mario finds it lodged in his Kart's exhaust pipe. He then glides to Peach's Castle when Mario gets there to tell him he couldn't find the key across the entire game.
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After that, he takes the diamond key from Full Moon Island thinking that that was the right key, then sunbathes on Mushroom Island until Mario arrives. He then gets trapped in the Lamp Scam in the yellow streamer area after swiping a key for the hotel thinking it's the right key. In the blue streamer world, he gets stuck in the gears of The House of Tricky Ninjas after swiping the Master Key for Shogun Studios thinking it was the right key. He then goes and looks for the key to Peach's Castle, so Mario can get in. Then, when the castle gets lifted up, he gets stuck in a wall that didn't get lifted.
In Origami King, he drives his brother to Peach's Castle at the beginning of the game.
But his most notable appearance is near the end of the game before the final area, where he uses his kart to bring Mario and Huey to Black Bowser's Castle (Huey makes a reference to the Luigi's "Death Stare" from Mario Kart 8). Luigi can be found in several locations in Color Splash around Prism Island, where Mario can use cutout to find him. However, he later appears once the player completes the game in the music player where he is shown relaxing on the beach and listening to music, while his 3D counterpart and the Mario duo are shown running in the background. Paper Luigi is absent unlike the other cast members such as his brother, Bowser and the princess. In Sticker Star, Luigi makes multiple cameo appearances in the environment and is able to be interacted with using Kersti's Paperize ability (Luigi is found in the boss stage of a world, usually in the background). Nevertheless, after the battle, Luigi is rescued once more and returns to Mario's party until their next adventure. Dimentio then merges himself, Luigi, and the Chaos Heart to form Super Dimentio. During the final battle with Count Bleck, Luigi is once again captured, only this time by the scheming Dimentio. Once Mario finally defeats him (and his vehicle of choice, the Brobot L-Type) in battle, however, Luigi comes to his senses and becomes a full member of Mario's team. L, a recurring enemy throughout the game. This capture leads to Luigi's transformation into Mr. Before joining the party, however, Luigi is captured and controlled by Count Bleck. In Super Paper Mario, Luigi appears as a playable member of Mario's party.
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After Mario's quest is over, Luigi returns to Rogueport, where his adventures are publicized in the Super Luigi series of items. He even acquires a party of his own, composed mostly of variations of common series enemies. During breaks in his adventure, he stays in Rogueport, where Mario can hear stories about Luigi's continuing adventures in the Waffle Kingdom. Luigi is recruited by the leaders of the Waffle Kingdom after Princess Eclair is kidnapped by the evil Chestnut King.
In The Thousand-Year Door, Luigi goes on his own adventure while Mario is away. He was one of the people that powered up the stars with his wish (Which is to sleep on the top bunk.) During the game's finale, Luigi leads the parade celebrating Peach's safe return. He keeps a diary detailing Mario's adventures (and his jealousy for Mario's luck), which he hides beneath the floorboard of their room. Having narrowly escaped Princess Peach's castle before it was lifted into the sky, he has little to do but stay home and protect the house. In Paper Mario, Luigi spends most of his time at the Mario Bros.' house.